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| Provedor de dados: |
Agronomy
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| País: |
Brazil
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| Título: |
Chemical and instrumental characterization of pectin from dried pomace of eleven apple cultivars - doi: 10.4025/actasciagron.v33i3.7125
Chemical and instrumental characterization of pectin from dried pomace of eleven apple cultivars - doi: 10.4025/actasciagron.v33i3.7125
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| Autores: |
Sato, Mariana de Fátima; Universidade Estadual de Ponta Grossa
Rigoni, Dayana Carla; Universidade Estadual de Ponta Grossa
Canteri, Maria Helene Giovanetti; Universidade Tecnológica Federal do Paraná
Petkowicz, Carmen Lúcia de Oliveira; Universidade Federal do Paraná
Nogueira, Alessandro; Universidade Estadual de Ponta Grossa
Wosiacki, Gilvan; Universidade Estadual de Ponta Grossa
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| Data: |
2011-06-22
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| Ano: |
2011
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| Palavras-chave: |
5.07.00.00-6 apple pomace
Dietary fibers
Pectin
Degree of esterification Ciência e Tecnologia de Alimentos apple pomace
Dietary fibers
Pectin
Degree of esterification
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| Resumo: |
Pectic substances from eleven samples of dried apple pomace were extracted using an acid procedure (100 mM HNO3, 10 min., 80ºC), dried, ground and stored in a P2O5 atmosphere. The degree of esterification was determined by the classical titrimetric method and confirmed by the instrumental FTIR method. The samples showed an average DE of 73% and the typical fingerprint in IR spectrogram. The steric exclusion chromatograms obtained with the multi-angle laser light scattering (MALLS) and refraction index (RI) detectors showed that all samples had a high molar fraction eluted at 36-38 min., another large polysaccharide family had an elution time around 43 min, and some samples showed yet another low molecular oligosaccharide that appeared at 58-60 min. Gas chromatography of alditol acetate allowed estimates of the proportion of the neutral sugar in the samples. The ratio of galacturonic acid and rhamnose may give the average size of the galacturonan fraction. These results showed that yields of pectin extracted by the same acid procedure were slightly different. However, the degree of esterification of pectin was similar, with both factors pointing to the best sources in this group of varieties.
Pectic substances from eleven samples of dried apple pomace were extracted using an acid procedure (100 mM HNO3, 10 min., 80ºC), dried, ground and stored in a P2O5 atmosphere. The degree of esterification was determined by the classical titrimetric method and confirmed by the instrumental FTIR method. The samples showed an average DE of 73% and the typical fingerprint in IR spectrogram. The steric exclusion chromatograms obtained with the multi-angle laser light scattering (MALLS) and refraction index (RI) detectors showed that all samples had a high molar fraction eluted at 36-38 min., another large polysaccharide family had an elution time around 43 min, and some samples showed yet another low molecular oligosaccharide that appeared at 58-60 min. Gas chromatography of alditol acetate allowed estimates of the proportion of the neutral sugar in the samples. The ratio of galacturonic acid and rhamnose may give the average size of the galacturonan fraction. These results showed that yields of pectin extracted by the same acid procedure were slightly different. However, the degree of esterification of pectin was similar, with both factors pointing to the best sources in this group of varieties.
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| Tipo: |
Caracterização química e instrumental
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| Idioma: |
Inglês
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| Identificador: |
http://periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/7125
10.4025/actasciagron.v33i3.7125
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| Editor: |
Universidade Estadual de Maringá
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| Formato: |
application/pdf
application/pdf
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| Fonte: |
Acta Scientiarum. Agronomy; v. 33, n. 3 (2011); 383-389
Acta Scientiarum. Agronomy; v. 33, n. 3 (2011); 383-389
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| Direitos: |
DECLARATION OF ORIGINALITY AND CESSATION OF COPYRIGHTI Declare that current article is original and has not been submitted for publication, in part or in whole, to any other national or international journal. I also declare that once published in the Acta Scientiarum. Agronomy, a publication of the Universidade Estadual de Maringá, it will not be submitted by me or by any co-author to any other scientific communication mean. In my name and in the name of co-authors, I shall cede the copyright of the above mentioned article to the Universidade Estadual de Maringá and I declare that I know that the non-observance of this norm may make me liable for the penalties contemplated in the Law for the Protection of Authors’ Rights (Act 9609 of the 19th February 1998).
DECLARACIÓN DE ORIGINALIDAD Y CESIÓN DE DERECHOS DE AUTOR Declaro que el presente artículo es original, no fue sometido a la publicación en cualquier otro periódico nacional o internacional, sea en parte o en su totalidad. Declaro, aun, que una vez publicado en la revista Acta Scientiarum. Agronomy, editado por la Universidad Estadual de Maringá, éste jamás será sometido por mí o por cualquier uno de los demás coautores a cualquier otro periódico. A través de este instrumento, en mi nombre y en nombre de los demás coautores, por ventura existentes, cedo los derechos de autor del referido artículo a la Universidad Estadual de Maringá y declaro estar informado de que la no observancia de este compromiso someterá al infractor las sanciones y penas previstas en la Ley de Protección de Derechos de Autor (Nº9609, de 19/02/98).
DECLARAÇÃO DE ORIGINALIDADE E CESSÃO DE DIREITOS AUTORAISDeclaro que o presente artigo é original, não tendo sido submetido à publicação em qualquer outro periódico nacional ou internacional, quer seja em parte ou em sua totalidade. Declaro, ainda, que uma vez publicado na revista Acta Scientiarum. Agronomy, editada pela Universidade Estadual de Maringá, o mesmo jamais será submetido por mim ou por qualquer um dos demais co-autores a qualquer outro meio de divulgação científica. Através deste instrumento, em meu nome e em nome dos demais co-autores, porventura existentes, cedo os direitos autorais do referido artigo à Universidade Estadual de Maringá e declaro estar ciente de que a não observância deste compromisso submeterá o infrator a sanções e penas previstas na Lei de Proteção de Direitos Autorias (Nº9609, de 19/02/98).
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